Answer to Question 1
e
Answer to Question 2
The 21-cm radiation is another example of a forbidden line, which is an emission line from cold, neutral hydrogen gas in the interstellar medium. A hydrogen atom consists of one proton and one electron. The ground state has two energy levels, leaving two ways for the electron to spin. If the electron is spinning one way, it can flip over and spin the other way, releasing excess energy as a photon with a wavelength of 21 cm.
That transition is statistically very unlikely, and it isn't detected in laboratories on Earth because the gas is too dense and warm, and the atoms collide too often. In space, however, hydrogen atoms collide only rarely, and hydrogen atoms can go undisturbed for millions of years, allowing them to produce the 21-cm emission line.