Pyrrole is a weak base because:
A)
the nitrogen lone pair is part of the aromatic system.
B)
the nitrogen lone pair is in an
sp2-hybridized orbital.
C)
the nitrogen lone pair is on a highly electronegative atom.
D)
the nitrogen lone pair is easily deprotonated
E)
the nitrogen lone pair is easily protonated.
Question 2In imidazole,
A)
the chemistry is more like a diene than like an aromatic compound.
B)
the chemistry is more like an isolated alkene than an aromatic compound.
C)
N
1 is more basic than N
3.
D)
both N
3 and N
1 are equally basic.
E)
N
3 is more basic than N
1.
Question 3The decreasing order of basicity of the following is:
A)
1 > 2 > 3
B)
1 > 3 > 2
C)
3 > 2 > 1
D)
2 > 1 > 3
E)
3 > 1 > 2
Question 4Pyridine is a weaker base than aliphatic tertiary amines because
A)
the N is
sp2 hybridized in pyridine and
sp3 hybridized in aliphatic amines.
B)
there are no unshared electrons on the N in pyridine.
C)
the electrons on the N in pyridine are delocalized around the ring.
D)
the N in pyridine is already protonated.
E)
the unshared electron pair on N in pyridine is part of the aromatic p system.