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Author Question: The oxidation of Cr3+ to CrO42 can be accomplished using Ce4+ in a buffered solution. The following ... (Read 111 times)

jrubin

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Question 1

The oxidation of Cr3+ to CrO42– can be accomplished using Ce4+ in a buffered solution. The following data were obtained:
 
Relative
Initial Rate
[Ce4+]0
[Ce3+]0
[Cr3+]0
 
1
2.0 × 10–3
1.0 × 10–2
3.0 × 10–2
 
2
4.0 × 10–3
2.0 × 10–2
3.0 × 10–2
 
4
4.0 × 10–3
1.0 × 10–2
3.0 × 10–2
 
16
8.0 × 10–3
2.0 × 10–2
6.0 × 10–2

Determine the order in the rate law of the species Ce4+.

 
Reference: Ref 12-7


1
2
3
–1
–2

Question 2

The oxidation of Cr3+ to CrO42– can be accomplished using Ce4+ in a buffered solution. The following data were obtained:
 
Relative
Initial Rate
[Ce4+]0
[Ce3+]0
[Cr3+]0
 
1
2.0 × 10–3
1.0 × 10–2
3.0 × 10–2
 
2
4.0 × 10–3
2.0 × 10–2
3.0 × 10–2
 
4
4.0 × 10–3
1.0 × 10–2
3.0 × 10–2
 
16
8.0 × 10–3
2.0 × 10–2
6.0 × 10–2

Determine the order in the rate law of the species Ce3+.

 
Reference: Ref 12-7


1
2
3
–1
–2


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Marked as best answer by jrubin on Mar 21, 2021

fur

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jrubin

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Reply 2 on: Mar 21, 2021
Excellent


steff9894

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Reply 3 on: Yesterday
YES! Correct, THANKS for helping me on my review

 

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