Author Question: Which synthesis will yield cyclopentanone from 1-methylcyclopentane? (Read 31 times)

markburs · **on:** Feb 17, 2022

Question 1

Propose a synthesis of propanoic acid from acetylene.
◦ 1. Br2/CCl4; 2. xs NaNH2; 3. H2O
◦ 1. NaNH2; 2. CH3CH2Br followed by 1. O3; 2. H2O
◦ 1. BH3/THF; 2. H2O2, NaOH
◦ NaOEt followed by 1. BH3/THF; 2. H2O2, NaOH
◦ t-BuOk followed by 1. Hg(OAc)2, H2O; 2. NaBH4

Question 2

Which synthesis will yield cyclopentanone from 1-methylcyclopentane?

◦ 1. Br2/CCl4; 2. xs NaNH2; 3. H2O
◦ t-BuOk followed by 1. Hg(OAc)2, H2O; 2. NaBH4
◦ NaOEt followed by 1. Hg(OAc)2, H2O; 2. NaBH4
◦ t-BuOk followed by 1. Hg(OAc)2 , H2O3 2. NaBH4
◦ Br2/ hv, followed by KOtBu, followed by 1. O3; 2. DMS

dsfhkjdfaskjfdsjk · **Reply #1 on:** Feb 17, 2022

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