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Author Question: In order to determine the identity of a particular lanthanide metal (M), a voltaic cell is ... (Read 76 times)

elizabeth18

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Question 1

If an electrolysis plant operates its electrolytic cells at a total current of 1.2 × 106 amp, how long will it take to produce one metric ton (one million grams) of Mg(s) from seawater containing Mg2+? (1 faraday = 96,485 coulombs)

1.8 h
1.8 days
55 min
0.92 h
0.46 year

Question 2

In order to determine the identity of a particular lanthanide metal (M), a voltaic cell is constructed at 25°C with the anode consisting of the lanthanide metal as the electrode immersed in a solution of 0.0594 M MCl3, and the cathode consisting of a copper electrode immersed in a 1.00 M Cu(NO3)2 solution. The two half-reactions are as follows:
M(s) → M3+(aq) + 3e
Cu2+(aq) + 2e→ Cu(s)
The potential measured across the cell is 2.64 V. What is the identity of the metal?
Reduction Half-Reaction
E° (V)
Cu2+(aq) + 2e→ Cu(s)
0.34
Ce3+(aq) + 3e→ Ce(s)
–2.336
Dy3+(aq) + 3e→ Dy(s)
–2.295
Eu3+(aq) + 3e→ Eu(s)
–1.991
Gd3+(aq) + 3e→ Gd(s)
–2.279
Sm3+(aq) + 3e→ Sm(s)
–2.304
 


Ce
Eu
Dy
Gd
Sm


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Marked as best answer by elizabeth18 on Mar 21, 2021

Shshxj

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elizabeth18

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Reply 2 on: Mar 21, 2021
Wow, this really help


bigcheese9

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Reply 3 on: Yesterday
Thanks for the timely response, appreciate it

 

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