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Author Question: Which is a plausible mechanism for the following reaction if the rate law is 2 O3 3 O2 (Read 45 times)

drink

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Question 1

What is the rate law for the following reaction and its mechanism?

2 O3→ 3 O2 (overall reaction)
O3→ O2 + O∙ (slow)
O∙ + O3→ 2 O2 (fast)

◦ Rate = k[O3]
◦ Rate = k[O3]2
◦ Rate = k[O3]2/[O2]
◦ Rate = k[O3]/[O2]
◦ Rate = k[O3][O2]

Question 2

Which is a plausible mechanism for the following reaction if the rate law is

2 O3→ 3 O2

◦ 2 O3→ O2 + O4  (slow)
O4→ 2 O2 (fast)
◦ 2 O3→ O6 (slow)
O6→ O4 + O2 (fast)
O4→ 2 O2 (slow)
◦ 2 O3→ O4- + O2+ (slow)
O4-→ O2 + O2- (fast)
O2- + O2+→ 2 O2 (slow)
◦ O3 O2 + O∙ (fast)
O∙ + O3→ 2 O2 (slow)
◦ O3 O2+ + O- (fast)
O- + O3→ O2 + O2- (slow)
O2- + O2+→ 2 O2 (fast)


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Marked as best answer by drink on Jul 8, 2021

randomguy133

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drink

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Reply 2 on: Jul 8, 2021
Excellent


dyrone

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Reply 3 on: Yesterday
Gracias!

 

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