The heat of solution of ammonium chloride is 15.2 kJ/mol. If a 6.134 g sample of NH4Cl is added to 65.0 mL of water in a calorimeter at 24.5°C, what is the minimum temperature reached by the solution? (The specific heat of water = 4.18 J/g·°C; the heat capacity of the calorimeter = 365. J/°C.)
◦ 18.6°C
◦ 19.7°C
◦ 21.9°C
◦ 27.1°C
◦ 30.4°C