Author Question: How to find the valence electron of transitional elements? (Read 1322 times)

stevenposner

  • Hero Member
  • *****
  • Posts: 608
how to find the valence electron of MO?
is there a formula to find their valence electron?



clippers!

  • Hero Member
  • *****
  • Posts: 828
Translation:

How to find the number of valence electrons for a transitional element?

How many valence electrons does MO (Molybdenum) have?

http://answers.yahoo.com/question/index?qid=20071203134233AASWPwh

There are six of them



Related Topics

Need homework help now?

Ask unlimited questions for free

Ask a Question

Melanie

  • Full Member
  • ***
  • Posts: 204
The periodic table tells it all. The transition elements start with their outer electrons being in a 4s orbital in which there are 2 electrons which are donated. Then the whole row has a valence of 2+ to start with.  Then B Groups start with 3d1 electrons, which also can be donated.  That gives Sc two valeneces of 2+ and 3+.  Next is Ti with 2+ and 4+  V tells you its valence!  etc
There is also another factor to consider and that is when the 3d orbitals are completely half-filled it has more stablitlity as all the electrons have the same spin
Cu can be one or two +  and Zn is 2+ only because the 3d orbital is filled, and it can donmate the two 4s2 electrons.  Good luck.  Isn't this interesting?.



bobbysung

  • Hero Member
  • *****
  • Posts: 519
It is easy to determine the number of valence e? a TM metal has (provided you have a PT!).  Just find it in the PT and look which group it is in and that gives you the number of valence e?.  Ti (Z= 22) is in Group 4 and so has four valence e?.  Re (Z= 75) is in Group 7 and has seven valence e?, Ag (Z = 47) is in Group 11 and hence has eleven valence e? , and so on.  Up to Group 7 the maximum oxidation state exhibited by a TM is its Group number.  Ti(IV) as in TiO2; and Mn(VII) is found in [MnO4]^-.  Fe does not form any Fe(VIII) cmpds, but Ru(VIII) and Os(VIII) are found in the tetroxides RuO4 and OsO4.  This is the maximum oxdn number known.
The problem comes in how these valence e? occupy the nd and (n+1)s valence atomic orbitals.  Let's deal with with the 1st Row TM (Ti ?Cu) first. In the gas phase the uncharged atoms have the e? configuration [Ar] 3d^n 4s^2  We will not discuss why the higher energy 4s AOs are occupied first  but it is fully understood.  The exceptions are Cr: [Ar] 3d^5 4s^1 and Cu [Ar] 3d^10 4s^1.  A hand-waving argument of extra stability associated with half-filled and completely-filled d shells is used.  Just be content that it is a quantum mechanical effect called spin exchange.  When the 1st Row TM forms the M^2+ or M^3+ ion (the common oxidation states of 1st Row TM) the higher energy 4s e? are lost first.  Thus Cr(III) is [Ar] 3d^3. Take Fe(0)(g) : Group 8 so eight v e? [Ar] 3d^6 4s^2;
Fe(II): [Ar] 3d^6; Fe(II): [Ar] 3d^5
When you get to the 2nd Row you throw all these "rules" out the window.  You can look up the Wikipedia entries (RH panel) for Ru, Rh and Pt and see if the half-filled d shell works.   So only an expert will know what the configuration is in the gas phase and questions like this should not be given to undergrads until 4th yr.  However Mo is in Group 6 and has an e? config [Kr] 4d^5 5s^1 so the half -illed d shell works here (but W the third row member of Group 6 is [Xe] 5d^4 6s^2 !).  So the best answer quoted by vekkus4 is wrong on two counts.  Once again when forming the cations the 5s e? are lost first: Mo(III) is [Kr] 4d^3.



 

Did you know?

Hippocrates noted that blood separates into four differently colored liquids when removed from the body and examined: a pure red liquid mixed with white liquid material with a yellow-colored froth at the top and a black substance that settles underneath; he named these the four humors (for blood, phlegm, yellow bile, and black bile).

Did you know?

You should not take more than 1,000 mg of vitamin E per day. Doses above this amount increase the risk of bleeding problems that can lead to a stroke.

Did you know?

To combat osteoporosis, changes in lifestyle and diet are recommended. At-risk patients should include 1,200 to 1,500 mg of calcium daily either via dietary means or with supplements.

Did you know?

Every flu season is different, and even healthy people can get extremely sick from the flu, as well as spread it to others. The flu season can begin as early as October and last as late as May. Every person over six months of age should get an annual flu vaccine. The vaccine cannot cause you to get influenza, but in some seasons, may not be completely able to prevent you from acquiring influenza due to changes in causative viruses. The viruses in the flu shot are killed—there is no way they can give you the flu. Minor side effects include soreness, redness, or swelling where the shot was given. It is possible to develop a slight fever, and body aches, but these are simply signs that the body is responding to the vaccine and making itself ready to fight off the influenza virus should you come in contact with it.

Did you know?

Alcohol acts as a diuretic. Eight ounces of water is needed to metabolize just 1 ounce of alcohol.

For a complete list of videos, visit our video library