All of the following are byproducts of -oxidation, except: a. ...

[craiczarry]

All of the following are byproducts of -oxidation, except:
 a. Acetyl CoA
  b. ADP
  c. NADH
  d. FADH2
  e. All of these are byproducts of -oxidation.

Question 2

All of the following describe -oxidation, except:
 a. Two-carbon units are eliminated during each cycle.
  b. The process employs NAD+ as an oxidant.
  c. The process is the primary route to fatty acid degradation.
  d. The 2-carbon groups are eliminated from the methyl end of the fatty acid.
  e. Fatty acids are attached to coenzyme A during the process.

Question 3

When treated with base and heat, the following diketone undergoes an intramolecular aldol reaction followed by dehydration to produce cis-jasmone, a perfume component. Draw the structure of the product.
 
   

Question 4

Identify the intermediate imine that results from the following reaction.
 
   

Question 5

Predict the major aldol product of the following reaction.
 
   

Question 6

How would you prepare the following compound using an alkylation reaction?
 
   

Question 7

Draw the structure of the diastereomer that is formed preferentially in the following reaction:
 
   

Question 8

Identify products a and b.
 
   

Question 9

Rank the following hydrogens in terms of decreasing acidity (most acidic > least acidic):
 
   

Question 10

Which of the following does not possess an enol form? Explain your choice.
 
   

Question 11

Which of the following are intermediates in the acid catalyzed aldol reaction of propanal to form 2-methyl-pent-2-enal?
   

  1.
  enol
  2.
  enolate
  3.
  tetrahedral carbonyl intermediate
  4.
  aldol
   
   
  a.
  only 1 and 2
   
  b.
  only 1, 3 and 4
   
  c.
  only 2, 3 and 4
   
  d.
  1, 2, 3 and 4

[pallen55]

Answer to Question 1

b

Answer to Question 2

d

Answer to Question 3



Answer to Question 4



Answer to Question 5



Answer to Question 6



Answer to Question 7



Answer to Question 8



Answer to Question 9

b > c > a

Answer to Question 10

C, this structure does not contain -hydrogen atoms.

Answer to Question 11

b

[craiczarry]

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[cdmart10]

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