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Author Question: Under certain conditions the reaction H2O2 + 3I + 2H+ I3 + 2H2O occurs by the following series of ... (Read 85 times)

nevelica

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Under certain conditions the reaction H2O2 + 3I + 2H+→ I3 + 2H2O occurs by the following series of steps:
 
k1
 
Step 1.
 
H2O2 + H+H3O2+
 
k–1
 
Step 2.
 
H3O2+ + I→ H2O + HOI
(slow, rate constant k2)
 
Step 3.
 
HOI + I→ OH + I2
(fast, rate constant k3)
 
Step 4.
 
OH + H+→ H2O
(fast, rate constant k4)
 
 
Step 5.
 
I2 + I→ I3
(fast, rate constant k5)

The rate constant k for the reaction would be given by:

 
Reference: Ref 12-17


k = k2
k = k2k3
k = k2K
k = k5
k = Kk2k3k4k5


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Marked as best answer by nevelica on Mar 21, 2021

Eazy416

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nevelica

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Reply 2 on: Mar 21, 2021
Thanks for the timely response, appreciate it


TheNamesImani

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Reply 3 on: Yesterday
Excellent

 

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