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Author Question: Draw alternative chair conformations for each substituted cyclohexane and state which chair is more ... (Read 58 times)

casperchen82

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Draw alternative chair conformations for each substituted cyclohexane and state which chair is more stable.
 
 
 
 

Question 2

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Question 3

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Question 4

Draw structural formulas for the cis and trans isomers of 1,2-dimethylcyclopropane.

Question 5

Draw structural formulas for the cis and trans isomers of hydrindane. Show each ring in its most stable
  conformation. Which of these isomers is the more stable?



Question 6

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 />

Shown above are the trans and cis isomers of hydrindane. Note that the cis-hydrindane displays some distortion
from the ideal cyclohexane ring structure. The result is that the trans-hydrindane is the more stable.

"

Question 7

Trans-1,4-di-tert-butylcyclohexane exists in a normal chair conformation. Cis-1,4-di-tert-butylcyclohexane,
  however, adopts a twist-boat conformation. Draw both isomers and explain why the cis isomer is more stable in the twistboat conformation.



Question 8

How many different staggered conformations are there for 2-methylpropane? How many different eclipsedconformatio ns are there?
   



Question 9

Torsional strain resulting from eclipsed C-H bonds is approximately 4.2 kJ (1.0 kcal)/mol, and that for
  eclipsed C-H and C-CH3 bonds is approximately 6.3 kJ (1.5 kcal)/mol. Given this information, sketch a graph of energy
  versus dihedral angle for propane.



Question 10

Write IUPAC names for these alkanes and cycloalkanes.
 
 

Question 11

Each of the following compounds is either an aldehyde or a ketone (Section 1.3C). Which structural
  formulas represent the same compound? Which represent constitutional isomers?


 
 



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Answer to Question 2



Answer to Question 3

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 />"

Answer to Question 4



Answer to Question 5





casperchen82

  • Member
  • Posts: 540
Reply 2 on: Aug 23, 2018
Thanks for the timely response, appreciate it


hollysheppard095

  • Member
  • Posts: 339
Reply 3 on: Yesterday
Great answer, keep it coming :)

 

Did you know?

People about to have surgery must tell their health care providers about all supplements they take.

Did you know?

Bisphosphonates were first developed in the nineteenth century. They were first investigated for use in disorders of bone metabolism in the 1960s. They are now used clinically for the treatment of osteoporosis, Paget's disease, bone metastasis, multiple myeloma, and other conditions that feature bone fragility.

Did you know?

It is believed that the Incas used anesthesia. Evidence supports the theory that shamans chewed cocoa leaves and drilled holes into the heads of patients (letting evil spirits escape), spitting into the wounds they made. The mixture of cocaine, saliva, and resin numbed the site enough to allow hours of drilling.

Did you know?

The calories found in one piece of cherry cheesecake could light a 60-watt light bulb for 1.5 hours.

Did you know?

The use of salicylates dates back 2,500 years to Hippocrates's recommendation of willow bark (from which a salicylate is derived) as an aid to the pains of childbirth. However, overdosage of salicylates can harm body fluids, electrolytes, the CNS, the GI tract, the ears, the lungs, the blood, the liver, and the kidneys and cause coma or death.

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