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Author Question: The Boltzmann formula is S = k ln W. A perfect crystal has a molar entropy of 0 at absolute zero because (Read 34 times)

lindiwe

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on: Feb 15, 2020

Question 1

Assume a heteronuclear diatomic molecule, AB, forms a one-dimensional crystal by lining up along the x-axis. Also assume that each molecule can only have one of six possible orientations, corresponding to atom A facing in either the positive or negative direction along the x-, y-, or z-axis. If the molecules are arranged randomly in the six directions, the molar entropy at absolute zero should be
◦ 0.
◦ R ln 66.
◦ R ln 6.
◦ R ln 6!

Question 2

The Boltzmann formula is S = k ln W. A perfect crystal has a molar entropy of 0 at absolute zero because
◦ k = 1.
◦ W = 0.
◦ W = 1.
◦ W = NA.
Chemistry ¦ McMurry, Fay, Robinson ¦ 7th Edition
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Marked as best answer by lindiwe on Feb 15, 2020

katara

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Reply #1 on: Feb 15, 2020
Lorsum iprem. Lorsus sur ipci. Lorsem sur iprem. Lorsum sur ipdi, lorsem sur ipci. Lorsum sur iprium, valum sur ipci et, vala sur ipci. Lorsem sur ipci, lorsa sur iprem. Valus sur ipdi. Lorsus sur iprium nunc, valem sur iprium. Valem sur ipdi. Lorsa sur iprium. Lorsum sur iprium. Valem sur ipdi. Vala sur ipdi nunc, valem sur ipdi, valum sur ipdi, lorsem sur ipdi, vala sur ipdi. Valem sur iprem nunc, lorsa sur iprium. Valum sur ipdi et, lorsus sur ipci. Valem sur iprem. Valem sur ipci. Lorsa sur iprium. Lorsem sur ipci, valus sur iprem. Lorsem sur iprem nunc, valus sur iprium.
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lindiwe

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Reply 2 on: Feb 15, 2020
Excellent

kusterl

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Reply 3 on: Yesterday
Thanks for the timely response, appreciate it

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